Standard deviation is a measure of how spread out a set of numbers is around their average. A small standard deviation means the numbers cluster tightly near the average; a large one means they scatter widely. In investing it is applied to an asset's returns, where it becomes the standard measure of volatility: the statistic that puts a number on how much a fund or portfolio bounces around from period to period.
It is the same idea reported on statements and in fund fact sheets, almost always annualized and expressed as a percentage. A stock fund might show a standard deviation of 15% a year while a bond fund shows 4%, and the plain meaning is that the stock fund's yearly returns have historically strayed much further from their own average than the bond fund's have. Standard deviation is the statistic; volatility is the property it measures, which is why the two words are often used as if they were one.