Why this election exists is more interesting than the mechanics. A direct payment to a school for tuition is not a gift at all under section 2503(e). But section 529(c)(2)(A) makes plain that a contribution to a 529 plan is not a section 2503(e) qualified transfer, so the tuition-payment carve-out does not save it. The transfer-tax system therefore treats a 529 contribution as an ordinary gift, subject to the annual exclusion and, above that amount, to the contributor's lifetime exclusion. Superfunding is the concession Congress built into the same subsection: the spread election lets one large contribution occupy up to five years of exclusion room without cutting into the lifetime amount, so that front-loading a 529 while a child is young does not consume estate and gift-tax exclusion that the family may need later.
A superfunding election closes the annual-exclusion door to the same beneficiary for the same period. During the five-year spread the contributor cannot make additional gifts to that beneficiary under the annual exclusion, because the contributor is already using it. A gift the contributor makes to that beneficiary during any of those years, no matter the reason, applies against the lifetime exclusion or, if the direct-tuition carve-out of section 2503(e) applies, does not need to.
The election has a real estate-tax consequence. If the contributor dies during the five-year period, section 529(c)(4)(C) includes the portion of the contribution allocable to the calendar years beginning after the year of death back in the contributor's gross estate. So a contributor who superfunds in Year 1 and dies in Year 2 has the Year 3 through Year 5 allocations pulled back into the estate; the Year 1 and Year 2 portions stay out. That is why the election is often described as making the 529 "outside the estate," subject to a survival requirement.
The tax election is separate from the state plan's rules. State 529 programs impose their own contribution and account-balance ceilings, and some limit how much can be contributed in a year regardless of the federal election. A superfunding election is a federal gift-tax election and does not override a state plan's operational limits, so a family reaching the state cap after the first year of the election is not able to add more even though the exclusion room is theoretically available.
The election works per contributor and per beneficiary. Two parents can each elect the spread to the same beneficiary, and each set of grandparents can too, so more than one person can superfund the same child's account in the same year. The mechanics of gift-splitting between spouses under section 2513 are separate from the section 529 election but combine with it: a couple that elects to split gifts and both elect the five-year spread doubles the amount that can go in.