Where zeros come from. The SEC notes that investors "can purchase different kinds of zero coupon bonds in the secondary markets that have been issued from a variety of sources, including the U.S. Treasury, corporations, and state and local government entities." The Treasury's contribution is not an issue of new bonds at all but a program that takes existing ones apart.
Treasury STRIPS. The name stands for Separate Trading of Registered Interest and Principal of Securities. TreasuryDirect explains: "The idea of STRIPS is that the principal and each interest payment become separate securities that are treated individually. Each separated piece is a zero-coupon security that matures separately and, has only one payment." Its example is a bond with ten years remaining, which consists of one principal payment and twenty semiannual interest payments; stripped, "The one original security is now 21 separate new securities" with their own CUSIP identifiers. Three rules govern the program. First, eligibility: "Treasury securities with a fixed-principal, such as notes, bonds, and TIPS are eligible and may be stripped. Bills and FRNs can't be stripped." Second, access: "You can buy, hold, sell, and redeem STRIPS only through a financial institution, a broker, or dealer who handles government securities." They cannot be held in a TreasuryDirect account. Third, size: "The minimum face amount needed to STRIP is $100, and any par amount above that minimum must be a multiple of $100." A stripped security can also be reassembled if one institution gathers every remaining piece. The Treasury bond page mentions STRIPS in passing; this is the fuller account of what a holder actually owns.
Corporate and municipal zeros. A corporation can issue a bond with no coupon directly, and so can a state or local government. In the municipal market the MSRB distinguishes a traditional zero from a capital appreciation bond, which is economically similar but structured so that "the investment return is considered to be in the form of compounded interest rather than accreted original issue discount"; the difference matters to the issuer's debt limit more than to the holder's return.
Why the price moves more. A coupon bond returns part of its value every six months, so only part of it is exposed to a change in rates for the full term. A zero returns everything on the last day, so all of it is exposed for the full term. The SEC states the consequence: "Because zero coupon bonds pay no interest until maturity, their prices fluctuate more than other types of bonds in the secondary market." The bond duration page explains why a zero is the one case where duration equals maturity. The flip side is that a zero held to maturity has no coupons to reinvest and therefore locks in its purchase yield, a point the reinvestment risk page makes.
The planning use, and the tax catch. The SEC observes that long maturities "allow an investor to plan for a long-range goal, such as paying for a child's college education," because "an investor can put up a small amount of money that can grow over many years" to a known sum on a known date. The catch is in the same entry: "although no payments are made on zero coupon bonds until they mature, investors may still have to pay federal, state, and local income tax on the imputed or "phantom" interest that accrues each year." The tax law treats the discount as interest earned over the life of the bond; Publication 550 states that "All debt instruments that pay no interest before maturity are presumed to be issued at a discount. Zero coupon bonds are one example of these instruments." That accrual is original issue discount, reported each year on Form 1099-OID, and the original issue discount page covers how it is computed and the exceptions. Holding a taxable zero inside a tax-deferred account, or buying a municipal zero whose accrual is exempt, are two ways to avoid paying current tax on income not yet received; the SEC's entry mentions the second.