The mechanism is a certificate the employee files, which is why so many eligible people never get the benefit. Illinois publishes Form IL-W-5-NR, titled "Employee's Statement of Nonresidence in Illinois," and its instructions are direct: "You must complete Part 1 of this form if you are a resident of Iowa, Kentucky, Michigan, or Wisconsin ... and your wages are exempt from withholding of Illinois Income Tax under the reciprocal withholding agreements between Illinois and these states. You must file your completed Form IL-W-5-NR with your Illinois employer." New Jersey's equivalent is Form NJ-165, "Employee's Certificate of Nonresidence in New Jersey." Nothing happens by itself. An eligible commuter who never files the form has the work state's tax withheld all year.
The employer carries a matching obligation. Illinois tells employers: "You are required to have a copy of this form on file for each employee who is a resident of Iowa, Kentucky, Michigan, or Wisconsin; receives compensation paid in Illinois; and elects to claim exemption from withholding of Illinois Income Tax under the reciprocal withholding agreements." The certificate is a payroll record, not a filing with the state.
A short deadline sits inside the Illinois form and is easy to miss. "If you change your state of residence, you must notify your employer within ten days." Moving across the line in either direction changes which state's tax should be coming out, and the duty to say so rests on the employee.
The agreement covers wages and nothing else. The New Jersey Division of Taxation states it flatly about the Pennsylvania arrangement: "The Reciprocal Agreement covers compensation only. If you are self-employed or receive other income (ie., gain from the sale of property) that is taxable in both states, you must file a New Jersey nonresident return and report the income received." It also defines what compensation means for this purpose: "salaries, wages, tips, fees, commissions, bonuses, and other payments received for services rendered as an employee." A commuter with a rental property or a side business in the work state is still exposed there.
If tax was withheld anyway, the money is recovered by filing, not by asking payroll. New Jersey's guidance for a Pennsylvania resident who had New Jersey tax withheld is to file a New Jersey nonresident return to get a refund, and to file Form NJ-165 with the employer to stop the withholding going forward. The certificate is prospective.
A second, unrelated exemption often rides on the same form. Illinois Form IL-W-5-NR also serves a service member's spouse claiming exemption under the Military Spouses Residency Relief Act, which reaches a different set of people for a different reason. Meeting either test uses the same piece of paper, which is worth knowing because a reader searching for one may find the form described in terms of the other.
There is no register of state pairs, and that absence is the practical point. These are agreements between two revenue departments rather than federal law, so they are added, amended and ended without any central listing, and a table copied from anywhere becomes wrong quietly. The reliable question is not "which states have reciprocity" but "does the state my employer is in publish a certificate of nonresidence, and does it name my home state on it." That is a page on one revenue department's website, and it is current by construction.